Yes. Once you have your catalogs configured, the module allows you to use a CRON task to automatize the creation of these catalogs without having to re-enter the configuration parameters again. You can thus create as many different PDF catalogs as you like.
The PDF Catalogue Module will generate a specific link for each catalog. This link can be found at the bottom of the module configuration screen. You will then need to create as many CRON tasks as necessary for each catalog. Remember to space creations up so that your server does not get overloaded.
You will then be able to generate your catalogs automatically by category for instance, several times a week or a month according to your needs.